{栖岸计划}热力统计学2

物理
{栖岸计划}热力统计学2

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一位刷舒力的物竞生 更新于2026-4-29 10:19:00

补一段笔记,上述推导中,有$\bar v$这个数的取值没打出来,故在这里推导

$\bar{v} = v \int_0^\infty f(v) \cdot 4\pi v^2 dv \sim v \int_0^\infty dp$

$\bar{v} = \int_0^\infty f(v) \cdot 4\pi v^3 dv$

$\bar{v} = 4\pi \left( \frac{m}{2\pi kT} \right)^{\frac{3}{2}} \int_0^\infty e^{-\frac{m}{2kT} v^2} v^3 dv$


$G_4\left(\frac{m}{2kT}\right) = \frac{1}{2a^2}$


$\bar{v} = 4\pi \left( \frac{m}{2\pi kT} \right)^{\frac{3}{2}} \cdot \frac{1}{2 \left( \frac{m}{2kT} \right)^2}$


$\bar{v} = 2\pi \left( \frac{m}{2\pi kT} \right)^{\frac{3}{2}} \left( \frac{m}{2kT} \right)^{-2}$


$\bar{v} = 2π(π)^{-\frac{3}{2}} (\frac{m}{2kT})^{\frac{3}{2}}(\frac{m}{2kT})^{-2} = 2\pi ( \pi )^{-\frac{3}{2}} (\frac{m}{2kT})^{-\frac{1}{2}}$

$=2π (π)^{-\frac{3}{2}} (\frac{2kT}{m})^{-\frac{1}{2}}$

$= 2 π^{-\frac{1}{2}} \left( \frac{2kT}{m} \right)^{-\frac{1}{2}}$

$= \left( \frac{8kT}{m\pi} \right)^{\frac{1}{2}}$

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一位刷舒力的物竞生
1月前

放点状态方程,不要让这个帖太水

$du = -pdV + TdS$


$dU(V,S) = \left( \frac{\partial U}{\partial V} \right)_S dV + \left( \frac{\partial U}{\partial S} \right)_V dS$

$-P = \left( \frac{\partial U}{\partial V} \right)_S$, $T = \left( \frac{\partial U}{\partial S} \right)_V$

$\left( \frac{\partial U}{\partial V} \right)_S = \left( \frac{\partial U}{\partial S} \right)_V$ 为 Maxwell 关系框

$-\left( \frac{\partial P}{\partial S} \right)_V = \left( \frac{\partial T}{\partial V} \right)_S$ (C,S,V 的函数)

$dH(P,S) = \left( \frac{\partial H}{\partial P} \right)_S dP + \left( \frac{\partial H}{\partial S} \right)_P dS$

$H(P,S) = U + PV$ $\Rightarrow$ 焓

$d[H(P,S)] = -pdV + TdS + pdV + Vdp = TdS + Vdp$

$\frac{\partial}{\partial S} \left( \frac{\partial H}{\partial P} \right)_S = \frac{\partial}{\partial P} \left( \frac{\partial H}{\partial S} \right)_P$

$\left( \frac{\partial V}{\partial S} \right)_P = \left( \frac{\partial T}{\partial P} \right)_S$

亥姆霍兹自由能 $\Leftrightarrow dF = d[U - TS] = -pdV + TdS - TdS - SdT = -pdV - SdT$

$dF(V,T) = \left( \frac{\partial F}{\partial V} \right)_T dV + \left( \frac{\partial F}{\partial T} \right)_V dT$

$+\left( \frac{\partial P}{\partial T} \right)_V = -\left( \frac{\partial S}{\partial V} \right)_T$

吉布斯自由能 $\Leftrightarrow dG = d[U - TS + PV] = -SdT + Vdp$

$dG = \left( \frac{\partial G}{\partial P} \right)_T dP + \left( \frac{\partial G}{\partial T} \right)_P dT$

$\left( \frac{\partial V}{\partial T} \right)_P = -\left( \frac{\partial S}{\partial P} \right)_T$

Maxwell 关系:

$-\left( \frac{\partial P}{\partial S} \right)_V = \left( \frac{\partial T}{\partial V} \right)_S$ —— U 内能

$\left( \frac{\partial V}{\partial S} \right)_P = \left( \frac{\partial T}{\partial P} \right)_S$ —— H 焓

$\left( \frac{\partial P}{\partial T} \right)_V = \left( \frac{\partial S}{\partial V} \right)_T$ —— F 亥姆霍兹自由能

$\left( \frac{\partial V}{\partial T} \right)_P = -\left( \frac{\partial S}{\partial P} \right)_T$ —— G 吉布斯自由能

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KING Kevin
1月前

可以补一下一二三维麦克斯韦分布之间严格的数学推导吗

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一位刷舒力的物竞生 回复 KING Kevin
1月前
顶帖。