放点状态方程,不要让这个帖太水
$du = -pdV + TdS$
$dU(V,S) = \left( \frac{\partial U}{\partial V} \right)_S dV + \left( \frac{\partial U}{\partial S} \right)_V dS$
$-P = \left( \frac{\partial U}{\partial V} \right)_S$, $T = \left( \frac{\partial U}{\partial S} \right)_V$
$\left( \frac{\partial U}{\partial V} \right)_S = \left( \frac{\partial U}{\partial S} \right)_V$ 为 Maxwell 关系框
$-\left( \frac{\partial P}{\partial S} \right)_V = \left( \frac{\partial T}{\partial V} \right)_S$ (C,S,V 的函数)
$dH(P,S) = \left( \frac{\partial H}{\partial P} \right)_S dP + \left( \frac{\partial H}{\partial S} \right)_P dS$
$H(P,S) = U + PV$ $\Rightarrow$ 焓
$d[H(P,S)] = -pdV + TdS + pdV + Vdp = TdS + Vdp$
$\frac{\partial}{\partial S} \left( \frac{\partial H}{\partial P} \right)_S = \frac{\partial}{\partial P} \left( \frac{\partial H}{\partial S} \right)_P$
$\left( \frac{\partial V}{\partial S} \right)_P = \left( \frac{\partial T}{\partial P} \right)_S$
亥姆霍兹自由能 $\Leftrightarrow dF = d[U - TS] = -pdV + TdS - TdS - SdT = -pdV - SdT$
$dF(V,T) = \left( \frac{\partial F}{\partial V} \right)_T dV + \left( \frac{\partial F}{\partial T} \right)_V dT$
$+\left( \frac{\partial P}{\partial T} \right)_V = -\left( \frac{\partial S}{\partial V} \right)_T$
吉布斯自由能 $\Leftrightarrow dG = d[U - TS + PV] = -SdT + Vdp$
$dG = \left( \frac{\partial G}{\partial P} \right)_T dP + \left( \frac{\partial G}{\partial T} \right)_P dT$
$\left( \frac{\partial V}{\partial T} \right)_P = -\left( \frac{\partial S}{\partial P} \right)_T$
Maxwell 关系:
$-\left( \frac{\partial P}{\partial S} \right)_V = \left( \frac{\partial T}{\partial V} \right)_S$ —— U 内能
$\left( \frac{\partial V}{\partial S} \right)_P = \left( \frac{\partial T}{\partial P} \right)_S$ —— H 焓
$\left( \frac{\partial P}{\partial T} \right)_V = \left( \frac{\partial S}{\partial V} \right)_T$ —— F 亥姆霍兹自由能
$\left( \frac{\partial V}{\partial T} \right)_P = -\left( \frac{\partial S}{\partial P} \right)_T$ —— G 吉布斯自由能